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Metal-Dielectric Interfaces in Gigascale Electronics

Thermal and Electrical Stability

Specificaties
Gebonden, 149 blz. | Engels
Springer New York | 2012e druk, 2011
ISBN13: 9781461418115
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Springer New York 2012e druk, 2011 9781461418115
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Samenvatting

Metal-dielectric interfaces are ubiquitous in modern electronics. As advanced gigascale electronic devices continue to shrink, the stability of these interfaces is becoming an increasingly important issue that has a profound impact on the operational reliability of these devices. In this book, the authors present the basic science underlying  the thermal and electrical stability of metal-dielectric interfaces and its relationship to the operation of advanced interconnect systems in gigascale electronics. Interface phenomena, including chemical reactions between metals and dielectrics, metallic-atom diffusion, and ion drift, are discussed based on fundamental physical and chemical principles. Schematic diagrams are provided throughout the book to illustrate  interface phenomena and the principles that govern them. Metal-Dielectric Interfaces in Gigascale Electronics  provides a unifying approach to the diverse and sometimes contradictory test results that are reported in the literature on metal-dielectric interfaces. The goal is to provide readers with a clear account of the relationship between interface science and its applications in interconnect structures. The material presented here will also be of interest to those engaged in field-effect transistor and memristor device research, as well as university researchers and industrial scientists working in the areas of electronic materials processing, semiconductor manufacturing, memory chips, and IC design.

Specificaties

ISBN13:9781461418115
Taal:Engels
Bindwijze:gebonden
Aantal pagina's:149
Uitgever:Springer New York
Druk:2012

Inhoudsopgave

<p>Preface</p><p>1. Introduction<br>1.1 Metal-dielectric interfaces in IC chips<br>1.2 Materials choices<br>1.3 Thermal and electrical stability</p><p>2. Metal-Dielectric Diffusion Processes: Fundamentals<br>2.1  Thermal diffusion<br>2.2  Field-enhanced ion drift<br>2.3  Thermodynamics and chemical interactions<br>2.4  Summary</p><p>3. Experimental Techniques<br>3.1 Test structures<br>3.2 Electrical measurements<br>3.3 Elemental characterizations<br>3.4 Summary</p><p>4. Al-Dielectric Interfaces<br>4.1 Al-SiO<sub>2</sub> interface<br>4.2 Al/low-k dielectric interfaces<br>4.3 Chemical identification of Al-ion drift<br>4.4 SiO<sub>2</sub> as a dielectric barrier against Al-ion drift<br>4.5 Summary</p><p>5. Cu-Dielectric Interfaces<br>5.1 Stability of Cu-SiO<sub>2</sub> in an oxygen-free environment<br>5.2 Instability of Cu-SiO<sub>2</sub> in an oxygen-containing environment<br>5.3 Origin of Cu ions in SiO<sub>2</sub><br>5.4 Cu ion diffusivity inside SiO<sub>2</sub><br>5.5 Cu ions in porous low-k dielectrics<br>5.6 Pre-cleaning of Cu/low-k dielectrics<br>5.7 Cu atoms in porous low-k dielectrics<br>5.8 Dielectrics containing no oxygen<br>5.9 Summary</p>6. Barrier Metal-Dielectric Interfaces<br>6.1 Barrier metals on SiO<sub>2</sub><br>6.2 Barrier metals on low-k dielectrics<p><p>7. Self-Forming Barriers<br>7.1 General considerations<br>7.2 Cu(Al) self-forming barrier<br>7.3 Cu(Mg) self-forming barrier <sub>           </sub><br>7.4. Cu(Mn) self-forming barrier<br>7.5 Refractory metal self-forming barrier alloys<br>7.6 Summary</p><p>8. Kinetics of Ion Drift<br>8.1 Ion distribution simulations<br>8.2 Leakage current<br>8.3 C-V characteristics<br>8.4 Summary</p><p>9. Time-Dependent Dielectric Breakdown (TDDB) and Future Directions<br />9.1 Time-dependent dielectric breakdown (TDDB)<br>9.2 Dielectric pore-sealing<br>9.3 Resistance-switching memory<br>9.4 Summary</p>

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        Metal-Dielectric Interfaces in Gigascale Electronics